Search results for "chemistry [Water]"
showing 9 items of 2369 documents
Experimental Constraints on the Deep Magma Feeding System at StromboliVolcano, Italy
2009
International audience; New experiments have been performed on a high-K basalt (PST-9) from Stromboli volcano, Italy, to constrain the physical conditions of golden pumice magmas at their storage level and discuss their petrogenesis. Fluid-present, H2O- and CO2-bearing, near-liquidus experiments were performed at 11508C between 100 and 400MPa and under oxidizing conditions. Glasses were analyzed by Fourier transform IR spectroscopy and their H2O and CO2 concentrations compared with those in glass inclusions.Most glass inclusions cluster near the 200MPa isobar, suggesting entrapment at a depth of ~8 km. Golden pumice magmas have viscosities of 7.9 Pa s and densities of 2.48-2.57 g/cm3. Compo…
Ultra-high temperature metamorphism recorded in Fe-rich olivine-bearing migmatite from the Khondalite Belt, North China Craton
2018
International audience; We document the first occurrence of Fe‐rich olivine‐bearing migmatitic metapelite in the Khondalite Belt, North China Craton. Petrological analyses revealed two exotic assemblages of orthopyroxene+spinel+olivine and orthopyroxene+spinel+cordierite. Phase relation modelling suggests that these assemblages are diagnostic of ultra‐high temperature (UHT) metamorphism in the Fe‐rich system, with temperatures from 1,000 to 1,050°C at 0.6 GPa. U–Th–Pb SIMS analyses on zircon reveal a similar age of c. 1.92 Ga for the olivine‐bearing migmatite and an adjacent gabbronoritic intrusion that is therefore identified as the heat source for the UHT metamorphism. These results, coup…
Alteration-Induced Volcano Instability at La Soufrière de Guadeloupe (Eastern Caribbean)
2021
International audience; Volcanoes are unstable structures that deform laterally and frequently experience mass wasting events. Hydrothermal alteration is often invoked as a mechanism that contributes significantly to volcano instability. We present a study that combines laboratory experiments, geophysical data, and large-scale numerical modeling to better understand the influence of alteration on volcano stability, using La Soufrière de Guadeloupe (Eastern Caribbean) as a case study. Laboratory experiments on variably altered (advanced argillic alteration) blocks show that uniaxial compressive strength, Young's modulus, and cohesion decrease as a function of increasing alteration, but that …
A model of degassing for Stromboli volcano
2010
International audience; A better understanding of degassing processes at open-vent basaltic volcanoes requires collection of new datasets of H2O–CO2–SO2 volcanic gas plume compositions, which acquisition has long been hampered by technical limitations. Here, we use the MultiGAS technique to provide the best-documented record of gas plume discharges from Stromboli volcano to date. We show that Stromboli's gases are dominated by H2O (48–98 mol%; mean, 80%), and by CO2 (2–50 mol%; mean, 17%) and SO2 (0.2–14 mol%; mean, 3%). The significant temporal variability in our dataset reflects the dynamic nature of degassing process during Strombolian activity; which we explore by interpreting our gas m…
A CO2-gas precursor to the March 2015 Villarrica volcano eruption
2017
We present here the first volcanic gas compositional time-series taken prior to a paroxysmal eruption of Villarrica volcano (Chile). Our gas plume observations were obtained using a fully autonomous Multi-component Gas Analyser System (Multi-GAS) in the 3 month-long phase of escalating volcanic activity that culminated into the 3 March 2015 paroxysm, the largest since 1985. Our results demonstrate a temporal evolution of volcanic plume composition, from low CO$_2$/SO$_2$ ratios (0.65-2.7) during November 2014-January 2015 to CO$_2$/SO$_2$ ratios up to ≈ 9 then after. The H$_2$O/CO$_2$ ratio simultaneously declined to <38 in the same temporal interval. We use results of volatile saturatio…
X-ray tomographic method for measuring three-dimensional deformation and water content distribution in swelling clays
2015
A non-invasive method for simultaneous measurement of the 3D displacement field and the water content distribution of a wetted solid material is developed. The method is based on comparison of X-ray tomographic images of a material sample in the reference state and in the wetted and deformed state. The deformation and water content analyses were successfully compared with numerical results for a cylindrical rubber test sample under axial compression, and with gravimetric results from axially wetted and sliced cylindrical bentonite samples, respectively. The methods were applied in a 4D study (three spatial dimensions and time) of wetting and deformation of purified swelling bentonite doped …
Analysis of the Potential of an Increase in Yeast Output Resulting from the Application of Additional Process Wastewater in the Evaporator Station
2019
This paper reports the results of an analysis of process wastewater streams in the context of an increase in yeast production. This research is based on the analysis of data from the biggest yeast factory in Europe. The research presented in this paper involves the analysis of the influence of direction of additional wastewater into the evaporator station on yeast production. In the process wastewater, nitrogen is mainly present in organic forms. The analysis reported in this paper involves the concentration of total nitrogen in wastewater streams, as it is the main parameter applied to determine the amount of wastewater that can be applied in agricultural fields. Directing additional waste…
Photoluminescence properties of S2 molecule trapped in Melanophlogite
2015
We studied the photoluminescence properties of a sample of SiO2-clathrate Melanophlogite, a crystalline microporous material which is found in nature as a rare mineral. Upon β irradiation, the material displays an intense light emission under near-UV illumination. We studied in detail this optical activity by steady-state and time-resolved photoluminescence measurements as a function of temperature. The spectroscopic properties we find can be ascribed to a population of quasi-free molecules trapped within each of the two different types of cage available in the structure of this clathrate, although the spectroscopic properties of the guest molecules are affected by their interactions with t…
Stable carbon and oxygen isotope fractionation in bivalve (Placopecten magellanicus) larval aragonite
2008
Abstract The relationship between stable isotope composition (δ13C and δ18O) in seawater and in larval shell aragonite of the sea scallop, Placopecten magellanicus, was investigated in a controlled experiment to determine whether isotopes in larval shell aragonite can be used as a reliable proxy for environmental conditions. The linear relationship between δ13CDIC and δ13Caragonite (r2 = 0.97, p δ 13 C DIC = 1.15 ( ± 0.05 ) ∗ δ 13 C aragonite - 0.85 ( ± 0.04 ) The relationship between δ13CDIC and δ13Caragonite described for P. magellanicus resulted in larval shell aragonite that was depleted on average by 1.82‰ (SD = 0.22‰, range = 1.1–2.1‰) from predicted equilibrium values based on the r…